[RUS]
SB LPI
Samara Branch of P.N. Lebedev Physical Institute of the Russian Academy of Sciences
Samara Branch of LPI
Structure
The Laboratory of Coherent Optics
The Laboratory for Laser-Induced Processes
The Laboratory of Physicochemical Kinetics
Theoretical Sector Group
Center for Laboratory Astrophisics
Seminar 2021
Publications
Contacts
The Center for Laboratory Astrophysics
Head of the Grant and the Center, Ralph Ingo Kaiser
Project Coordinator and Deputy of the Head of the Center V. N. Azyazov

The Center for Laboratory Astrophysics is being created to complete the tasks of megagrant “The origin and evolution of organic molecules in our Galaxy” (agreement between the Ministry of Science and Higher Education of the Russian Federation and Lebedev Physical Institute No. 075-15-2021-597).

The head of both the grant and the Center is the Professor of the University of Hawaii at Manoa (USA) Ralph Ingo Kaiser. Project coordinator from the Samara Branch of the Lebedev Physical Institute (SB LPI), Director of the SB LPI V. N. Azyazov.

The purpose of the project is to study the mechanisms of complex organic compounds formation on ice-covered nanoparticles in molecular clouds and in star-forming regions.

Research methods:

  • conducting astrophysical experiments that reproduce the conditions of the interstellar medium;
  • calculations of the molecules electronic structure;
  • astrochemical modeling;
  • astronomical observations.
The components of the Interdisciplinary Center for Laboratory Astrophysics, their scientific tasks RO1-RO5 and the connections between them
Key tasks:
  • design, construction and launch of a new generation facility for the study of cryogenic surface processes (CSP).
  • Building a unified concept of the molecular mass growth fundamental processes, which lead to the main classes of organic compounds in extraterrestrial ice, based on the experimental data obtained in the project.
  • Testing the mechanisms of synthesis of organics such as functionalized aromatics of RNA and DNA relevant to the origins of life theme in molecular clouds and star-forming regions by comparison with the results of astrochemical modeling and astronomical observations.
Expected results:
  • Fundamental regularities of radiation-induced physicochemical processes in low-temperature interstellar ice.
  • Mechanisms of organic compounds growth in interstellar ice.
  • A refined concept of the organic compounds evolution in space.
Collaboration:
  • Samara National Research University,
  • University of Hawaii at Manoa, USA,
  • International University of Florida (Florida International University, USA).
Employees of the Center:

Head of The Center; Dr.habil.
Deputy of the Head, leading research associate, DSci;
senior research associate, Ph.D;
leading research associate, DSci;
Evseev Mikhail Mikhailovich
postgraduate student;
chief research associate, DSci;
senior research associate, DSci;
Krasnoukhov Vladislav Sergeevich
postgraduate student;
leading research associate, DSci;
junior research associate, postgraduate student;
research associate, PhD Physics;
research associate, PhD Physics;

Events: Media about us: Publications:
  • He, C., Fujioka, K., Nikolayev, A. A., Zhao, L., Doddipatla, S., Azyazov, V. N., ... & Kaiser, R. I. (2022). A chemical dynamics study of the reaction of the methylidyne radical (CH, X 2 Π) with dimethylacetylene (CH3 CCCH3, X1 A1g). Physical Chemistry Chemical Physics, 24(1), 578-593. DOI: 10.1039/D1CP04443E
  • Pershin, A., Azyazov, V., Torbin, A. P., Mikheyev, P. A., Mebel, A. M., & Kaiser, R. (2021). Ozone Destruction due to the Recombination of Oxygen Atoms. The Journal of Chemical Physics. https://doi.org/10.1063/5.0064361
  • Yang, Z., Doddipatla, S., Kaiser, R. I., Nikolayev, A. A., Azyazov, V. N., & Mebel, A. M. (2021). On the Synthesis of the Astronomically Elusive 1-Ethynyl-3-Silacyclopropenylidene (c-SiC4H2) Molecule in Circumstellar Envelopes of Carbon-rich Asymptotic Giant Branch Stars and Its Potential Role in the Formation of the Silicon Tetracarbide Chain (SiC4). The Astrophysical Journal Letters, 908(2), L40. https://doi.org/10.3847/2041-8213/abde36
  • Zhao, L., Doddipatla, S., Kaiser, R. I., Lu, W., Kostko, O., Ahmed, M., ... & Fischer, F. R. (2021). Gas-phase synthesis of corannulene–a molecular building block of fullerenes. Physical Chemistry Chemical Physics. https://doi.org/10.1039/D0CP06537D
  • Yang, Z., Doddipatla, S., Kaiser, R. I., Krasnoukhov, V. S., Azyazov, V. N., & Mebel, A. M. (2021). Directed Gas Phase Formation of the Elusive Silylgermylidyne Radical (H3SiGe, X2A′′). ChemPhysChem, 22, 184-191. https://doi.org/10.1002/cphc.202000913
  • He, C., Nikolayev, A. A., Zhao, L., Thomas, A. M., Doddipatla, S., Galimova, G. R., ... & Kaiser, R. I. (2021). Gas-Phase Formation of C5H6 Isomers via the Crossed Molecular Beam Reaction of the Methylidyne Radical (CH; X2Π) with 1, 2-Butadiene (CH3CHCCH2; X1A'). The Journal of Physical Chemistry A, 125(1), 126-138. https://doi.org/10.1021/acs.jpca.0c08731
  • Z. Yang, C. He, S. Goettl, R. I. Kaiser, V. N. Azyazov, A. M. Mebel, Directed Gas-Phase Formation of Aminosilylene (HSiNH2; X1A'): The Simplest Silicon Analogue of an Aminocarbene, under Single-Collision Conditions, JACS, 143, 14227-14234 (2021). https://doi.org/10.1021/jacs.1c05510
  • L. Zhao, M. Prendergast, R. I. Kaiser, B. Xu, W. Lu, M. Ahmed, A. H. Howlader, S. F. Wnuk, A. S. Korotchenko, M. M. Evseev, E. K. Bashkirov, V. N. Azyazovde, A. M. Mebel, A molecular beam and computational study on the barrierless gas phase formation of (iso)quinoline in low temperature extraterrestrial environments, Phys. Chem. Chem. Phys., 23, 18495 (2021). https://doi.org/10.1039/d1cp02169a